2 edition of Continuous flow method for the study of adsorption of metal ions by humic acid. found in the catalog.
Continuous flow method for the study of adsorption of metal ions by humic acid.
Eric Hans Hartmann
Published
1978
by University ofBirmingham in Birmingham
.
Written in
Edition Notes
Thesis (M.Sc.) - University of Birmingham, Dept of Chemistry, 1978.
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| Open Library | OL20661556M |
Clay and humic-acid sols were prepared from humic acid extracted from soil and clay fractions (Cited by: 7. increase the migration of heavy metal ions in water, which is also an important issue in water treatment [13,5]. It was reported than an intake of a huge amount of humic acid might be one of the etiological factors for the Blackfoot disease [1,2]. Therefore, the mineralization of the presence of humic acid in drinking and other process water is of.
Here, we conducted a systematic study using a continuous-flow seawater flume system to assessmore» In the day exposure, the adsorbent exposed in dissolved Fe-spiked seawater (low DOM/high Fe) and humic acid-spiked seawater (high DOM/high Fe) showed lower uranium adsorption loadings (73% and 56% of adsorption loading, respectively) than the. Adsorption of humic acid on bentonite, Chemistry, Applied Clay Science 38 () 51– 4) Jinming D, Francis W, Nigel G, and Joo Hwa T, Adsorption of Humic acid by powdered activated carbon in saline water conditions, Desalination ()
Composite magnetic microspheres of chitosan (CTS) and quaternary ammonium chitosan derivative (HTCC) were prepared by inverse suspension method. Tripolyphosphate (TPP) and glutaraldehyde were used successively to co-crosslink the microsphere matrix. The morphology was analyzed using optical microscopy and scanning electron microscopy (SEM), while the Cited by: 1. Humic substances are organic compounds that are important components of humus, the major organic fraction of soil, peat, and coal (and also a constituent of many upland streams, dystrophic lakes, and ocean water).For a long era in the 19th and 20th centuries, humic substances were often viewed through a lens of acid–base theory that described humic acids, as organic acids, .
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A metal-complexation model was used to compare the adsorption characteristics of insolubilized humic acid (IHA) with those of HA. The results showed that two different types of acidic groups were present on HA and the insolubilization process scarcely influenced the metal-complexation constant of acidic groups; however, the number of available Cited by: A continuous flow method for studying adsorption and desorption of pesticides in soil colloid systems.
Proc. XI th Br. Weed Control Conf (Brighton) Grice, R E., M.H.B. Hayes, P R. Lundie, and M.H. Cardew. A continuous flow method for studying adsorption of organic chemicals by a humic acid preparation.
Chem. and : I.A. Law, J.J. Tuck, C.L. Graham, M.H.B. Hayes. Humic acids (HAs) can act as electron shuttles and mediate biogeochemical cycles, thereby influencing the transformation of nutrients and environmental pollutants.
HAs commonly complex with metals Cited by: In this study, illite-humic complexes were used to evaluate Ca2+, Cd2+, and Cu2+ adsorption and how this adsorption was affected by humic acids, differing in. In the present work we studied the role of humic acids in the heavy metal–soil interaction after the addition of different amounts of humic acids to a soil poor in organic matter.
Both adsorption isotherms and breakthrough curves of cadmium(II) and nickel(II) were by: Humic acid (HA) was impregnated onto powdered activated carbon to improve its Cu(II) adsorption capability. The optimum pH value for Cu(II) removal was 6.
The maximum adsorption capacity of HAimpregnated activated carbon was up to mgg−1, which is five times the capacity of virgin activated carbon. The adsorption processes were rapid and Cited by: Kinetic Study for Adsorption Humic Acid on Soil Minerals and reactive with heavy metal ions, that carboxylic groups dominate metal binding to humic acid.
In this study, a synthetic humic. In this study, three kinds of natural clay minerals (kaolin clay, montmorillonite and diatomaceous earth) were used to treat the raw water containing humic acid (HA) by adsorption/sedimentation. The results indicated that natural kaolin clay had no obvious effect on removing HA in water.
Using chitosan to modify montmorillonite and diatomaceous earth, the removal effect of the Author: Yu Heng Wang, Ying Xiong, Jing Nan Zhang, Yue Ting Zeng, Ji Rui Chen.
The interactions of metal ions with humic substances in molar ratio metal to ligand are investigated by spectroscopic technique with absorbance at nm for Fe (II), Cu (II) and Zn (II) and nm for Mn (II).
The complexes formed by humic and fulvic acid with metal ions was studied by molar ratio method and job’s plot method. The adsorption of different compounds such as gallic, tannic, and humic acids on an activated carbon at K has been studied.
The capacity of this carbon to adsorb gallic acid is much higher than for the other two acids, which has been explained on the basis of both their molecular size and ionization degree. The influence of dissolved Cr(NO3)3 on the adsorption of these acids Cited by: In this study, activated clay was added in chitosan slurry to prepare composite beads.
The adsorption isotherms and kinetics of two organic acids (tannic acid, humic acid) and two dyes (methylene blue, reactive dye RR) using composite beads, activated clay, and chitosan beads were by: A Donnan-type model for nonspecific binding of electrolyte ions has been combined with the non-ideal competitive adsorption (NICA) model for specific binding to produce a model for ion binding to humic substances.
The model considers site heterogeneity, non-ideality, multicomponent competition, and electrostatic interactions. The NICA-Donnan model was fitted to data for H.
In HA-M complexes, HA can change the properties of metal ions. For instance, metal solubility can be increased when metals are complexed with free HA or decreased when metals are scavenged by humic films on mineral surfaces 8. As a result, heavy metal (e.g., Cu, Pb, Ag, and Cd) bioavailability and toxicity are affected 9.
A previous study Cited by: Equilibrium and kinetic studies on the adsorption of humic acid by activated sludge and Bacillus subtilis Woranart Jonglertjunya* and Tidathip Lertchutimakul Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Salaya, Phutthamonthon, Nakhon Pathom, Thailand.
biosorption of metal ions. adsorption. process. Keywords: adsorption, humic acid, kinetic. s, nanofiber. Introduction. Humic. acid (H.
A) is a component of natural organic matter (NOM) in surface and ground water, which is. derived from the breakdown of plant biomass [1], [2]. A may cause a serious problem for drinking water.
production because. A can. form File Size: KB. Adsorption of Humic Acid onto Carbonaceous Surfaces: Atomic Force Microscopy Study - Volume 17 Issue 6 - Zhiguo Liu, Yuangang Zu, Ronghua Meng, Zhimin Xing, Shengnan Tan, Lin Zhao, Tongze Sun, Zhen ZhouCited by: In the present study, both the adsorption and coagulation characteristics of humic acid samples are evaluated subsequent to pretreatment by photocatalytic oxidation and ozonation.
The changes in preoxidized humic acid solutions are assessed in relation to the alterations induced in the UV-vis and fluorescence spectroscopic properties. The choice of pH to study the metal adsorption on to humic acids is based on the availability of the element in solution, as well as in the amount of surface charges of the solid phase.
At very low pH values, there is a competition for the active sites of macromolecules between metal ions and H + ions from the solution. As the pH rises, the. the humic acid adsortion remained constant and this indicating the equilibrium has been established.
0 25 50 75 0 50 Contact time (min) % Adsorption 85oC 65oC 45oC 25oC. Fig. 1 Effect of temperature on humic acid adsorption. from peat water. From Fig.1, it also shows that the amount of humic acid. treatment. However, humic acid (HA) is a major component of organic matter in waste water.
It can cause serious fouling problems during membrane filtration processes for water treatment []. The pollutant caused by humic acid on the membrane surface and within membrane pores lead to flux decline, and restrictFile Size: KB.
ADSORPTION OF SOIL-DERIVED HUMIC ACID BY SEVEN CLAY MINERALS: A SYSTEMATIC STUDY REBECCA A. CHOTZEN,TAMARA POLUBESOVA*, BENNY CHEFETZ, AND YAEL G. MISHAEL* Department of Soil and Water Sciences, Faculty of Agriculture, Food and Environment, The Hebrew University of Jerusalem, P.O. RehovotIsrael File Size: 1MB.This study examines the influence of humic acids (HA) on adsorption of radium (Ra) ions onto coir pith (CP) in aqueous solution.
The adsorption behaviours of Ra ions onto CP under the influence of HA in aqueous solution were investigated in the series of batch mode adsorption experiments. The effects of various experimental conditions such as.The removal of Pb2+ in the aqueous solutions by adsorption onto insolubilized humic acid (IHA) is investigated.
The equilibrium isotherms were determined at pH under constant ionic strength and at different temperatures. At the same time, the paper has also analyzed the adsorption experimental data by using three different isotherm models: Langmuir, Frendlich and Linear .
